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Pore Structure and Diagenetic Evolution Features of Member-7 of Yanchang Formation in Qingcheng Area, Ordos Basin, NW China 
WANG Enze, WU Zhongbao, SONG Yanchen, SHI Kaibo, LIU Hangyu, LIU Bo
Acta Scientiarum Naturalium Universitatis Pekinensis    2022, 58 (2): 249-260.   DOI: 10.13209/j.0479-8023.2022.012
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Thin section and scanning electron microscope (SEM) observations, X-ray Diffraction (XRD) measurements, and mercury intrusion capillary pressure were selected to systematically research the lithology, physical properties, pore structure, and diagenetic features of member-7 of Yanchang Formation (Chang-7 Fm) in Qingcheng Area, Ordos Basin, NW China. The influences of pore structure and diagenetic processes of physical properties were revealed, and the gradual evaluation standard was proposed. The results show that the Chang-7 Fm sandstones are dominated by feldspathic litharenites. The average porosity and permeability are 9.7% and 0.06 mD, respectively, which can be classified as a set of tight sandstone reservoir. The reservoirs stay in mesodiagenesis B stage, and the physical properties are primarily controlled by mechanical compaction and dissolution. The coarser particle size and higher content of quartz and feldspar improve the anti-compaction ability of relatively high-quality reservoirs. Meanwhile, quartz and feldspar also provide material basis for dissolution, and are important control factors for the development of relatively high-quality reservoirs. The pore type and structure also have influences to the physical properties. The primary pore has excellent connectivity. The development of secondary pores is conducive to porosity increasement, but has little effect to permeability. Based on the fractal theory, the heterogeneity of reservoir’s pore network is quantified, and the results show that the heterogeneity is negative correlate with the porosity and permeability, which means that the complex pore network is not conducive for the development of high-quality reservoirs. According to the pore structure and physical properties, three categories can be identified of the Chang-7 Fm tight sandstones. Class I and II reservoirs have large particle size, and the pore system is dominated by primary pores with less heterogeneity, therefore, they are favorable exploration targets. Type III reservoir has small particle size, and mainly develops intercrystalline pores of clay minerals, possess strong heterogeneity of pore structure and poor physical properties, which is not the target of tight oil and gas exploration. 
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Origin of Mg-Rich-Fluids and Dolomitization of Lower Ordovician Penglaiba Formation at Tongguzibulong Outcrop in the Northwestern Margin of Tarim Basin
HE Yong, LIU Bo, LIU Hongguang, SHI Kaibo, WANG Yuanchong, JIANG Weimin
Acta Scientiarum Naturalium Universitatis Pekinensis    2018, 54 (4): 781-791.   DOI: 10.13209/j.0479-8023.2018.006
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Based on comprehensive analysis of field work, petrological and geochemical characteristics, the authors study the sources of dolomitizing fluids and the models of dolomitization of the Lower Ordovician Penglaiba Formation in Tongguzibulong Outcrop, the northwestern margin of Tarim Basin, China. Four types of
dolomite are recognized: euhedral-subhedral powder crystallized dolomite, euhedral-subhedral fine crystallized dolomite, subhedral-xenotopic medium crystallized dolomite and subhedral-xenotopic coarse crystallized dolomite. Powder-fine crystallized dolomite is distributed in the lower part of Penglaiba Formation, and has cloudy center surrounded by clear rim. With residual sand texture, inter-crystal pores and inter-partical pores, medium-coarse crystallized dolomite is distributed in the upper part of Penglaiba Formation. The REE patterns of dolomite and contemporaneous limestone rich in LREE and deplete in HREE, present a trait of unobvious Ce anomaly and Eu negative anomaly, the values of C-O isotope locate in the scope of contemporaneous marine dolomite, and Eu negative anomaly. All these denote that the dolomitizing fluid is normal or slightly concentrated seawater. Besides, Powder-fine crystallized dolomite present a low value of Fe, Mn and a high value of Sr, Ba, formed by reflux seepage dolomitization in penesaline seawater. Cloudy center surrounded by clear rim texture and multi-rimmed texture are the results of over-dolomitization. Medium-coarse crystallized dolomite with residual grain texture, interbedded with sand limestone, are controlled by high frequency sea level change. With a higher value of Fe, Mn and a lower value of Sr, Ba when compared with powder-fine crystallized dolomite, medium-coarse dolomite formed by the early reflux seepage dolomitization and intensified by the subsequent burial recrystallization.

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The Characteristics and Implication of Origin of the Giant Patch Dolomite of the Lower-Middle Ordovician in Wuligezitag Area NE Tarim Basin, China
WU Shuanglin, SHI Kaibo, LIU Hongguang, LIU Jianqiang, WANG Yuxi, LIU Bo
Acta Scientiarum Naturalium Universitatis Pekinensis    2016, 52 (3): 444-456.   DOI: 10.13209/j.0479-8023.2015.118
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Based on comprehensive analysis of field work, petrological and geochemical characteristics, this paper studies the characteristics and origin of giant patch dolomite of the Lower-Middle Ordovician HangGuletag Formation in Wuligezitag area, NE Tarim Basin, China. It can be seen in the field that the grayish yellow giant patch dolomite partially develops in the black thin-bedded micritic limestone, with an irregular boundary not controlled by sedimentation. The giant patches are several meters in size (the largest >10 m) which is larger than and quite different from the several-centimeter (decimeter) burrow-related dolomite or leopard fur dolomite. Microscopically, it consists of micro-finely and planare(s) dolomite crystals with a size near 100 μm. Besides, it is also characterized by its unique geochemical features: 1) δ13CPDB (−1.34‰-−0.62‰) accords with the range of Early Ordovician seawater while δ18OPDB (−8.01‰ -−4.79‰) is higher; 2) 87Sr/86Sr  (0.711000-0.711535, AVG=0.710863) is much higher than that of limestone and contemporaneous seawater; 3) average high Fe and Mn content (2001.32 and 601.73 μg/g, respectively) and low Sr and Ba (33.14 and 8.27 μg/g, respectively) content versus that of limestone; 4) dolomite has slightly negative Eu anomaly and similar REE composition and distribution patterns compared with limestone; 5) low order degree value (AVG=0.6). This study reveals that the dolomitization was related to fault and occurred in low-temperature and shallow-burial environment in Early-Middle Ordovician. Dolomitizing fluid was generated from the concentrated formation fluid in lower-middle member of HangGuletag Formation and underlying Tursaktag Group. Most Mg2+ came from the stabilization of quasi-stable carbonate minerals, and the transformation of clay minerals of (calcareous) mud in the limestone strata not only provided a little Mg2+ but caused the rise of 87Sr/86Sr. Dolomitizing fluid was likely to be richened in Xingdi-related normal fault and fractures which also acted as the main fluid pathways, and it finally caused the partial dolomitization of nearby limestone strata.

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Re-recognition of Deep Carbonate Dissolution Based on the Observation of in-situ Simulation Experiment
YANG Yunkun,LIU Bo,QIN Shan,LUO Ping,ZHANG Shanming,ZHOU Minghui,SHI Kaibo,TIAN Yongjing
Acta Scientiarum Naturalium Universitatis Pekinensis   
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A set of new carbonate dissolution in-situ experiments was designed to simulate the real burying process and to test its affection on fluid-rock reaction. By adoption DAC, the experimental process was controlled by the heater according to the paleothermal gradient of NE Sichuan. Experiment results indicate that limestone show precipitation with the increase of temperature and pressure. Dolomite is more stable than limestone in the whole experimental process, which shows a quite different result from the standpoint that dolomite is more dissoluble than limestone in high temperature and high pressure conditions. The “dissolution window” was not observed in the whole experimental process. The experimental researches may provide some new perspectives to the recognition of the formation and preservation mechanism for the deep carbonate reservoir.
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